麻豆淫院

(麻豆淫院Org.com) -- A collaboration between the Advanced Photon Source and Center for Nanoscale Materials at Argonne National Laboratory has "seen" the crystallization of nanoparticles in unprecedented detail.

鈥�Nanoscience is a hot issue right now, and people are trying to create self-assembled nanoparticle arrays for data and memory storage,鈥� Argonne assistant physicist Zhang Jiang said. 鈥淚n these devices, the degree of ordering is an important factor.鈥�

In order to call up a specific bit of data, it is ideal to store information on a two-dimensional crystal lattice with well-defined graphical coordinates. For example, every bit of information of a song saved on a hard drive must be stored at specific locations, so it can be retrieved later. However, in most cases, defects are inherent in nanoparticle crystal lattices.

鈥淒efects in a lattice are like potholes on a road,鈥� Argonne physicist Jin Wang said. 鈥淲hen you鈥檙e driving on the highway, you would like to know whether it is going to be a smooth ride or if you will have to zigzag in order to avoid a flat tire. Also, you want to know how the potholes form in the first place, so we can eliminate them.鈥�

Controlling the degree of ordering in nanoparticle arrays has been elusive. The number of nanoparticles a chemist can make in a small volume is astonishingly large.

鈥淲e can routinely produce 10¹⁴ particles in a few droplets of solution. That is more than the number of stars in the Milky Way Galaxy,鈥� Argonne nanoscientist Xiao-Min Lin. 鈥淭o find conditions under which nanoparticles can self-assemble into a crystal lattice with a low number of defects is quite challenging.鈥�

Because nanoparticles are so small, it is not easy to see how ordered the lattice is during the self-assembly process. Electron microscopy can see individual nanoparticles, but the field of view is too small for scientists to get a 鈥渂ig picture鈥� of what the ordering is like in macroscopic length scale. It also doesn鈥檛 work for wet solutions.

"With local ordering, one cannot assume the same order exists throughout the whole structure; it鈥檚 like seeing a section of road and assuming it is straight and well constructed all the way to the end,鈥� Wang said.

The same group of researchers at Argonne, together with their collaborators at the University of Chicago, discovered that under the right conditions, nanoparticles can and .

This allows the two-dimensional crystallization process to occur over a much longer time scale. 鈥淵ou typically don鈥檛 expect metallic particles to float. It is like throwing stones into a pond and expecting them to float on the surface,鈥� Lin said. 鈥淏ut in the nanoworld, things behave differently.鈥�

Using high-resolution X-ray scattering at the Advanced Photon Source (APS), Jiang and the others examined the crystallization process in unprecedented detail as it forms in real time. They discovered that the nanoparticle arrays formed at the liquid-air interface can enter a regime of a highly crystalline phase defined in the classical two-dimensional crystal theory. Only when the solvent starts to dewet from the surface, do defects and disorder begin to appear.

鈥淲e can probe the entire macroscopic sample and monitor what鈥檚 happening in real time,鈥� Jiang said. "This allows us to understand what parameters are important to control the self-assembly process.鈥�

With this level of understanding, the scientists hope that one day devices such as the iPod Nano can be made from nanoparticles.

A was published in Nano Letters.