麻豆淫院

(麻豆淫院Org.com) -- Carbon capture has long been identified as a critical technology needed to prevent global warming, but efficient and economical ways to do it have been hard to find.

A new process to capture and convert carbon dioxide, discovered by a chemist in the College of Liberal Arts and Sciences, has just been awarded a patent. It uses cheap catalysts, electricity, and heat to convert CO₂ and water into useful chemicals or fuels.

Steve Suib, Board of Trustees Distinguished Professor of Chemistry and the 2011 Connecticut Medal of Science winner, found a way to use metal oxides, such as manganese and zinc oxides, as catalysts in a conversion process that also uses heat and electricity.

The newly patented method can be run as a continuous, rather than a batch, process, to yield large amounts of a product. What is made depends on the catalyst used. Potential products include paraformaldehyde, used in disinfectants and in chemical processes in industry, or ethylene, the largest bulk chemical in the world, used in products such as milk bottles.

The process could also be used to generate hydrogen and a variety of hydrocarbons.

鈥淵ou can make a significant amount of material at high conversions over a long period of time,鈥� Suib says.

CO₂ and H₂O are abundant but hard to activate in a chemical process, Suib points out: 鈥淚t is difficult because both of those molecules are relatively stable.鈥�

The process was developed in Suib鈥檚 lab, and Ph.D. candidate Boxun Hu, soon to graduate, was heavily involved in the work, which will be published, Suib says.

The patent was granted in late June. It improves on an earlier process that Suib patented in 2009, which used a more expensive catalyst鈥攑latinum鈥攁nd produced little product. The earlier process was the subject of a 2010 paper in the journal .

Both patents are jointly held by UConn, through the Office of Technology Commercialization, and Catelectric Advanced Electrocatalysis, a company that began as part of UConn鈥檚 Technology Incubation Program. Catelectric specializes in improved catalysis processes.

Suib has received research grants from Catelectric to work on the process. He has also had extensive Department of Energy grant funding, and is the lead researcher on a $1.8 million DoE grant to make catalysts for a pilot biomass conversion plant that will be built at UConn.

Suib鈥檚 latest patent鈥攈e has about 50鈥攊s a combined process and composition of matter patent. While process patents can be hard to enforce, Suib says鈥攊t is difficult to tell whether a possible infringer is varying or using the same process鈥攖he composition of matter component of the patent makes infringement easier to pinpoint.

If the newly patented process is used, UConn would get royalties from the use.

The next step would be to take what is a rather crude, laboratory process and scale it up to the pilot plant stage for testing, and eventually to the manufacturing stage, Suib says.

The costs of heat and electricity used in the process would then be considerations. Electricity costs are high in Connecticut compared with other states, Suib notes. The technology of capturing heat, and even excess CO₂, from existing manufacturing plants might be considered, allowing factories to use their excess heat in a process that would result in making new chemicals.

The 鈥淏uck Rogers鈥� idea now being floated is to capture heat escaping from nuclear power plants and use that as a heat source, he says.

The effort to capture and convert CO₂ into useful products, mitigating global warming in the process, is one that has captured his interest: 鈥淎 lot of people say, 鈥榶ou just can鈥檛 do this鈥欌�攂ut those are the problems that are interesting.鈥�