麻豆淫院

(麻豆淫院Org.com) -- Researchers at the U.S. Department of Energy鈥檚 (DOE) Brookhaven National Laboratory and the Universidad San Francisco de Quito in Ecuador have found that, at just the right temperatures, nanoclusters form and improve the flow of electrical current through certain oxide materials. This work could be used in a number of industrial applications including spintronics, which exploit electrical and magnetic properties for use in solid-state electronics. The researchers鈥� findings appear in the Proceedings of the National Academy of Sciences during the week of December 12, 2011.

The unusually large variation in resistance to the flow of electricity in the presence of a magnetic field observed in some oxide materials is a phenomenon known as colossal magnetoresistance. The oxides involved in this research have a specific arrangement among the atoms that make up the material. The scientists found that, at particular temperatures in a magnetic field, nanoclusters about 10 atoms in size formed in these materials. These nanoclusters had electronic properties different from the material鈥檚 whole and were essential to the emergence of colossal magnetoresistance.

鈥淯ntil now, scientists could only speculate that nanoclusters play a critical role in colossal magnetoresistance. Our work pinpointing the nanoclusters with improved conductivity is a big step in understanding this phenomenon and the fundamental laws of materials,鈥� said Brookhaven physicist Jing Tao, lead author on the paper.

鈥淎s we cooled samples from room temperature to about 250 Kelvin (-23 degrees Celsius), we found that colossal magnetoresistance emerged as nanoclusters formed and became most dense,鈥� Jing explained. 鈥淲e saw the nanoclusters form and connect a path in the crystal, and the whole material became conducting.鈥�

These nanoclusters were thought to only act as insulators with different magnetic properties, Jing added. This work shows that these properties are temperature dependent. In the presence of a magnetic field and at the proper temperature, the nanoclusters become conductive and ferromagnetic to allow colossal magnetoresistance to occur.

For this research, scientists at the Universidad San Francisco de Quito in Ecuador grew crystals of manganite 鈥� manganese oxide doped with varying quantities of calcium and the rare-earth metal lanthanum. Scientists at Brookhaven then bombarded the crystals with beams of high-powered, negatively charged electrons using the Lab鈥檚 Transmission Electron Microscope to study their properties. As the electrons passed through the crystal, the scientists analyzed their paths and energy levels to determine properties such as structure and magnetism, as well as the nanoclusters鈥� role in the emergence of colossal magnetoresistance.

鈥淭hanks to the unique instruments at Brookhaven, we also found a new level of complexity in the material with colossal magnetoresistance,鈥� said Tao. 鈥淲e know now that these nanoclusters form and enable colossal magnetoresistance at certain temperatures, but we don鈥檛 yet know why or how they interact with the material as a whole.

鈥淚n the future when we learn more about the nanoclusters 鈥� for example, the details of their structure and whether they are charged 鈥� we can begin to improve the electrical performance of these materials.鈥�