Titania nanotubes go commercial: Potential use in fuel cells, solar panels

(Âé¶¹ÒùÔº)—Seven years ago, physics proÂfessor Latika Mennon's first gradÂuate stuÂdent said he wanted to "change the world." She knew of her experÂtise in making nanoporous aluÂminum oxide and believed an analÂoÂgous system with titaÂnium dioxide, or titania, could be useful in the develÂopÂment of fuel cells and solar panels.
"AluÂminum is more like an insuÂlator," Menon explained. "For solar cells you need semiÂconÂducÂtors. Titania is a semiconductor."
Using simple elecÂtroÂchemÂical methods, Menon's team develÂoped a mateÂrial made of neatly aligned, hollow, titania nanÂotubes. "It's an array of tubes," she said. "Just like lots of cylinÂders, or test tubes, arranged in parallel."
Menon explained that applying a voltage to a soluÂtion of chlorine-​​containing salts causes a piece of subÂmerged titaÂnium foil to oxiÂdize on the surÂface. Under cerÂtain conÂdiÂtions, the titania will morph into the highly aligned strucÂture she has described. "Since it's a self-​​assembly process, we don't have to worry about it, " Menon said.
The method is straightÂforÂward, cost effecÂtive and, perÂhaps most imporÂtantly, enviÂronÂmenÂtally friendly. As such, Menon's work doveÂtails with Northeastern's focus on conÂducting use-​​inspired research that solves global chalÂlenges in health, secuÂrity and sustainability.
Menon and her research team origÂiÂnally designed the mateÂrial to be used in alterÂnaÂtive energy appliÂcaÂtions, but she has found that it could be used in a host of other applications.
Backed by a $50,000 grant from the InnoÂvaÂtion Corps proÂgram of the National SciÂence FounÂdaÂtion, she is curÂrently working to bring the techÂnology into a comÂmerÂcial setting.
Menon's research team comÂprises MoniÂdipa Ghosh, a research assisÂtant, and entreÂpreÂneurial mentor Prashanth Makaram, cofounder of the biotech startup Alpha SzenÂszor, Inc., and a past member of proÂfessor Ahmed Busnaina's lab in Northeastern's Center for High Rate NanomanÂuÂfacÂturing.
Menon sugÂgested that the technology's tubular platÂform could be used as a filter, noting that its uniÂform morÂphology makes it ideal for this parÂticÂular application.
According to Menon, the titania nanÂotubes' bioÂcomÂpatÂible mateÂrial makes it appealing for use in agriÂculÂtural or cosÂmetics appliÂcaÂtions or as an alterÂnaÂtive hydrogen genÂerÂaÂtion catÂaÂlyst for fuel cells, which curÂrently use expenÂsive platÂinum wires.
She also said that the nanÂotubes can be easily removed from the foil surÂface as thin, coheÂsive sheets. This propÂerty could make the techÂnology useful for a variety of appliÂcaÂtions, including portable, flexÂible phoÂtoÂvoltaics and solar cells.
MoreÂover, the color of these thin sheets is deterÂmined by the diamÂeter of the nanÂotube. Since the dimenÂsions can be conÂtrolled through taiÂlored experÂiÂmental conÂdiÂtions, Menon's team could conÂceivÂably design phoÂtoÂvoltaic "paints" for the building and autoÂmoÂtive industries.
Provided by Northeastern University