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Development of atactic C-C main chain polymer with a high melting point

Polymers with carbon–carbon (C-C) bonds (C-C polymers) in the main chain skeleton such as polyethylene and polypropylene are important industrial materials and are utilized as common plastics.

Most C-C polymers have been prepared by vinyl polymerization, where starting materials (monomers) with a C=C double bond such as ethylene and propylene were used for their production. Researchers from Ehime University have succeeded in developing an alternative method for preparing C-C polymers using diazoacetate as a monomer, where the C-C bonds are constructed from C1 units derived from the monomer.

The polymers obtained by the latter method (C1 polymers) are expected to become new polymer materials with useful properties that cannot be obtained by vinyl polymerization. The work is published in the journal Macromolecules.

In general, imparting high crystallinity to polymers is an effective method for improving the strength and durability of the materials, and high crystallinity is achieved by high stereoregularity in the polymer main chain. Accordingly, polymers with low stereoregularity (atactic polymers) tend to be less valuable materials; for example, polypropylene can be a useful material only when its C-C bonds are highly stereoregulated. As for C1 polymers, whereas highly stereoregulated polymers with high crystallinity have been reported, atactic C1 polymers are amorphous with a relatively low melting point, as well.

In this study, the researchers have succeeded in synthesizing an atactic C1 polymer with a high melting point by incorporating an amide-linkage into its side-chain. As they expected, the amide-linkages suppress the side-chain mobility because of an inter- and intrachain hydrogen-bonding interaction among them, resulting in raising the melting point up to 130℃.

However, the incorporation of the identical amide-linkage into side-chains of a vinyl polymer was not effective in raising its melting point; thus, the higher melting point of the C1 polymer was realized because the dense-packing of its side chains greatly enhances the hydrogen-bonding interaction.

These results provide a new insight into the thermal properties of C-C polymers and is expected to be applied to new polymer material design.