麻豆淫院

Safety issues related to flammable electrolytes in lithium-ion batteries (LIBs) remain a major challenge for their extended application. The use of non-flammable phosphate鈭抌ased electrolytes has proven its validity in inhibiting the combustion of LIBs. However, the strong interaction between Li⁺ and phosphate leads to a dominant solid electrolyte interphase (SEI) with limited electronic shielding, resulting in poor Li⁺ intercalation at the graphite (Gr) anode when using high鈭抪hosphate鈭抍ontent electrolytes.

A study to address this issue was conducted by Prof. Jia Xie and Ph.D. Ziqi Zeng from the School of Electrical and Electronic Engineering, Huazhong University of Science and Technology.

"To mitigate this issue and improve Li⁺ insertion, we propose an 'In鈭扤鈭扥ut' strategy to render phosphate 'non鈭抍oordinative'. By employing a combination of strongly polar solvents for a 'block effect' and weakly polar solvents for a 'drag effect', the Li⁺鈭抪hosphate interaction is reduced."

"As a result, phosphate remains in the electrolyte phase ('In'), minimizing its impact on the incompatibility with the Gr electrode ('Out'). In the designed electrolyte, even if the content of TEP reaches over 60 wt.%, the Gr anode still achieves reversible Li⁺ de鈭抜ntercalation reaction. Meanwhile, the introduction of strongly polar solvents improves the dissociation of lithium salts, thereby making the electrolyte demonstrate excellent ion conductivity (5.94 mS/cm at 30 鈦癈)," Xie says.

A few implications thus emerge for designing non鈭抐lammable electrolytes: 1) the solvents' coordination ability with Li⁺ could be adjusted by "In鈭扤鈭扥ut" strategy; 2) the "drag effect" is universal interaction between weakly polar solvents and TEP, which affords more possibility for designing non鈭抐lammable electrolytes.

The study is in the journal Science China Chemistry.