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Apollo lunar mission samples reveal origins of lunar water and its connection to Earth's early history

Water samples from Apollo lunar mission reveal origins of lunar water and its connection to Earth's early history
δ18O vs. Δ′17O of our lunar samples (N = 28). Symbol colors relate to temperature, with 50 °C (blue), 150 °C (red), and 1,000 °C (black). Relevant meteorite (green) and micrometeorite (blue) groups are plotted. Most lunar water samples fall in or near enstatite chondrite-like values, likely representing indigenous lunar water. Samples fractionated toward a negative δ18O represent mixing between enstatite chondrite field and comets. Sample 10060 has the most negative Δ′17O, forming a mixing line toward the isotopic composition of its impactor (sample is 41% glass) and the lunar water value. Credit: Proceedings of the National Academy of Sciences (2024). DOI: 10.1073/pnas.2321069121

A team of international scientists has unveiled groundbreaking research on the origins of lunar water, offering insights that could reshape our understanding of the Earth-moon system and the broader solar system. in the journal Proceedings of the National Academy of Sciences, the pioneering study explores the isotopic signatures of lunar water, revealing a mix of indigenous and cometary sources.

The team analyzed water in nine samples from the Apollo , using a high-precision triple oxygen isotope technique. This method, developed by Dr. Morgan Nunn Martinez of the University of California, San Diego, separates water into its various binding phases—loosely bound, tightly bound, and trapped within minerals—via stepwise heating at 50°C, 150°C, and 1,000°C. Their findings provide crucial evidence that lunar water has a dual heritage: one part originating from early Earth-like material and another delivered through cometary impacts.

"This is a major step forward in unraveling where lunar water comes from," Dr. Maxwell Thiemens of the AMGC research group of the VUB explained. "Our data suggest that the moon inherited water tracing back to Earth's formation, followed by later contributions from comets, delivering the water reservoirs we see today."

Three key results are central to the report:

  1. An early Earth signature: The oxygen closely matches enstatite chondrites, a meteorite type believed to be the building blocks of the Earth.
  2. There are also clear signs of cometary contribution: A significant portion of lunar water shows isotopic similarities to comets.
  3. A reduced importance of solar wind: the study challenges the prevalent theory that the majority of was produced in situ via solar interactions with lunar silicates, presenting instead a complex mixing of sources.

This discovery is timely as nations and private enterprises intensify their efforts to establish permanent lunar bases. Understanding the water's origins and distribution could have significant implications for sustaining on the moon.

"The data not only enhance our understanding of the moon's past but also pave the way for future space exploration and resource utilization. These findings should redefine how we think about water as a resource for long-term lunar habitation," Thiemens concludes.

This research has the potential to shape lunar and for decades to come, offering a deeper connection between Earth's water-rich environment and the moon's arid surface. With Artemis missions on the horizon, this pioneering study provides a crucial foundation for future exploration and resource planning.

More information: Maxwell M. Thiemens et al, Triple oxygen isotopes of lunar water unveil indigenous and cometary heritage, Proceedings of the National Academy of Sciences (2024).

Citation: Apollo lunar mission samples reveal origins of lunar water and its connection to Earth's early history (2024, December 19) retrieved 31 July 2025 from /news/2024-12-apollo-lunar-mission-samples-reveal.html
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