First-ever real-time visualization of nanoscale domain response may boost ultrasound imaging technology

Ultrasound imaging is one of the most widely used diagnostic tools in modern medicine. Behind its noninvasive magic lies a class of materials known as piezoelectric single crystals, which can convert electrical signals into mechanical vibrations and vice versa.
Now, in a world-first, a research team from Kumamoto University has successfully visualized how tiny structures inside one of these crystals respond to electric fields in real time鈥攕hedding light on the dynamics of nanostructure in materials used in ultrasound probes. The work is published in the journal Applied 麻豆淫院ics Letters.
The team, led by Professor Yukio Sato from the Research and Education Institute for Semiconductors and Informatics (REISI), focused on a crystal known as PMN-PT (a solid solution of lead magnesium niobate and lead titanate), prized for its exceptional piezoelectric performance. It has been known that applying alternating current (AC) electric fields鈥攌nown as AC poling鈥攃an enhance the performance of these materials. But the exact mechanisms behind this improvement, and how overuse can actually degrade performance, remained a mystery.
In the , the team used a specialized in situ electron microscopy method developed at Kumamoto University, which allowed them to observe microscopic domain structures鈥攃alled ferroelectric nanodomains鈥攁s they responded to AC electric fields.
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Change of domain structure by short-time AC poling. TEM images (top row) and the corresponding domain structures (bottom row) after applying AC electric fields for 0.05 seconds (left column) and 2 seconds (right column), respectively. Credit: Applied 麻豆淫院ics Letters (2024). DOI: 10.1063/5.0232904 -
Change of domain structure by long-time AC poling. TEM images (top row) and the corresponding domain structures (bottom row) after applying AC electric fields for 2 seconds (left column) and 870 seconds (right column), respectively. Credit: Applied 麻豆淫院ics Letters (2024). DOI: 10.1063/5.0232904
What they saw was striking: just one cycle of an AC electric field at a strength of 12 kV/cm and 20 Hz significantly changed the domain structure.
Over time, shorter AC treatments caused some domain walls to grow and merge, potentially enhancing the material's properties. However, extended treatments led to the formation of vertically aligned microdomain bands that may hinder performance鈥攁 phenomenon consistent with over-poling.
"This is the first time we've been able to watch these nanoscale domains react in real time," says Professor Sato. "Understanding these changes is essential for refining the poling process and developing more efficient and longer-lasting medical imaging devices."
More information: Yukio Sato, Response of ferroelectric nanodomain to alternative-current electric fields in morphotropic-phase boundary Pb(Mg1/3Nb2/3)O3鈭扨bTiO3, Applied 麻豆淫院ics Letters (2024).
Journal information: Applied 麻豆淫院ics Letters
Provided by Kumamoto University