麻豆淫院

A research team led by Prof. Pavel Jungwirth at the Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences (IOCB Prague) has uncovered a previously unknown phenomenon that emerges during the transformation of a liquid from a nonmetal to a conductive metal.

In this transition, they observed a distinct phase in which the system spontaneously and rapidly flips between metallic and nonmetallic states鈥攚ithout settling in either for any meaningful length of time.

This newly proposed theory is grounded in high-level molecular modeling. The study, carried out in collaboration with the University of Oxford, the Faculty of Mathematics and 麻豆淫院ics at Charles University, and the J. Heyrovsk媒 Institute of 麻豆淫院ical Chemistry of the CAS, has been in Nature Communications.

Prof. Jungwirth and his colleagues have long been exploring the conditions under which substances shift from nonmetallic to metallic states. Their research challenges conventional ideas rooted in the fact that metals are typically solid, showing instead that certain liquids can exhibit interesting metallic behavior not present in solids.

One of their earlier models鈥攚here alkali metals such as lithium, sodium, or potassium are dissolved in liquid ammonia until the solution transitions from blue to a golden metallic state鈥�garnered attention in Science five years ago.

As alkali metals release electrons into the solution, the increasing number of free electrons begins to form a conduction band, turning the electrolyte liquid into a liquid metal.

The team at IOCB Prague developed a methodology that not only allows this transition to be calculated but also, in principle, verified experimentally using photoelectron spectroscopy at a synchrotron facility.

Building on these results, they've now used advanced molecular dynamics simulations to propose a new hypothesis: that between the nonmetal and metal phases, there exists a third phase characterized by ultrafast switching鈥攚ithin just tens of femtoseconds鈥攂etween the two.

"No one had previously realized that a system might oscillate between metallic and nonmetallic states on such a brief timescale. It simply hadn't been considered before," says Prof. Jungwirth. "We believe our theoretical predictions are accurate enough to warrant serious attention."

The team is now working to validate their findings experimentally and is searching for a laboratory equipped to detect these fleeting transitions.

"This won't be easy, because the switching happens incredibly fast鈥攐n the order of millionths of a millionth of a second," says Ph.D. student Marco Vitek, the study's first author. "The question is how to capture something that fast in an experiment. Our plan is to use ultrafast lasers, some of which we already have access to here at the institute."

If confirmed, the findings could open a new chapter at the boundary of physics and chemistry鈥攊ntroducing a fundamental physical process not yet covered in the literature.