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June 10, 2025

Novel coating shields iron from rust with 99.6% efficiency

Right: uncoated iron. Left: coated iron. Both shown after exposure to rust-promoting conditions. Credit: Linoy Amar
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Right: uncoated iron. Left: coated iron. Both shown after exposure to rust-promoting conditions. Credit: Linoy Amar

Researchers have developed a highly effective dual-layer coating that provides 99.6% protection against iron corrosion. The breakthrough combines a thin molecular primer with a durable polymer layer, creating a strong, long-lasting barrier against rust. This innovation could significantly reduce maintenance costs and extend the lifespan of iron-based materials used in construction, transportation, and manufacturing.

Researchers at the Hebrew University of Jerusalem have developed a highly effective new coating that can protect from with 99.6% efficiency. Led by Prof. Elad Gross from the NanoCenter and Institute of Chemistry at Hebrew University, the study introduces an innovative two-layer coating system that significantly improves upon existing methods for preventing corrosion. The work is in the journal Angewandte Chemie International Edition.

Iron is widely used in industries such as construction, transportation, and manufacturing, but it is highly prone to rust when exposed to air and moisture. Rust weakens the metal, leading to structural damage and costly repairs. While exist, many tend to degrade over time, offering limited long-term protection.

The new research presents a solution by combining two protective layers that work together to create a strong and long-lasting barrier. The first layer is an ultra-thin coating made of N-Heterocyclic Carbene (NHC) molecules, which form a tight bond with the iron surface.

FIB-SEM analysis of polymer-coated iron foils before a,b) and after c,d) their immersion in NaCl solution and exposure to potentiodynamic polarization measurements. The iron foils were coated with a crosslinked polymer network (CPN) with (a and c) and without (b and d) benzNHC monolayer as a binder. A protective layer of Iridium (Ir) was deposited on the polymer prior to FIB extraction. Credit: Angewandte Chemie International Edition (2025). DOI: 10.1002/anie.202422879
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FIB-SEM analysis of polymer-coated iron foils before a,b) and after c,d) their immersion in NaCl solution and exposure to potentiodynamic polarization measurements. The iron foils were coated with a crosslinked polymer network (CPN) with (a and c) and without (b and d) benzNHC monolayer as a binder. A protective layer of Iridium (Ir) was deposited on the polymer prior to FIB extraction. Credit: Angewandte Chemie International Edition (2025). DOI: 10.1002/anie.202422879

This primer layer ensures that the second layer—a polymer-based coating—sticks firmly, creating a highly stable and durable protective shield. Thanks to this improved adhesion, the coating remains intact even in , such as prolonged exposure to saltwater.

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Experiments showed that this dual-layer system dramatically reduced the amount of corrosion, with tests conducted in a highly corrosive saltwater environment confirming its exceptional efficiency. By forming a strong chemical connection between the iron and the protective layers, this method offers far greater durability than conventional coatings, which often wear down or peel off over time.

"This discovery offers a major leap forward in protecting iron from corrosion," said Prof. Gross. "By using a specially designed primer, we created a coating that is not only highly effective but also long-lasting. This could reduce maintenance costs, extend the lifespan of iron-based materials, and provide industries with a much more reliable solution."

This breakthrough has broad implications for industries that rely on iron and steel, from construction and transportation to infrastructure and manufacturing. By reducing the need for frequent repairs and replacements, this coating could also contribute to more sustainable and cost-effective material use.

More information: Linoy Amar et al, Self‐Assembled Monolayer of N‐Heterocyclic Carbene as a Primer in a Dual‐Layer Coating for Corrosion Protection on Iron, Angewandte Chemie International Edition (2025).

Journal information: Angewandte Chemie International Edition

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A dual-layer coating combining an N-heterocyclic carbene molecular primer with a polymer top layer achieves 99.6% efficiency in protecting iron from corrosion. The system forms a strong, durable barrier that resists degradation even in harsh environments, offering significantly improved longevity and potential cost savings for iron-based materials in various industries.

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