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Jarosite: A golden sponge to mop up metals

Jarosite: a golden sponge to mop up metals
Dr Niloofar Karimian studies how jarosite can be used to immobilise contaminants from acidic environments. Credit: CSIRO

Jarosite might not sparkle like a gem, but in the world of environmental geochemistry, it's a treasure.

For me, it's more than just a mineral. It's a storyteller. It captures and records the history of acidic environments, offering insight into past conditions, present risks, and future opportunities to clean-up contaminants.

Jarosite is a dusty yellow mineral you might see crusting the surface of mine tailings or dried-out wetlands.

It forms in highly acidic soils, when iron, sulfate and potassium or sodium come together under acidic, oxidizing conditions.

These conditions are common in mine waste sites. Known as (AMD), sulfide minerals react with air and water, creating highly acidic water loaded with .

In these harsh settings, jarosite starts to crystallize, forming hard, yellowish crusts on the surface of mine tailings.

At first, I saw it as just another mineral. But as I dug deeper, it became clear. Jarosite is far more than a passive bystander.

Cleaning up environmental contaminants

Jarosite has a hidden power. It can trap like arsenic, lead and antimony inside its structure.

But, locking up toxic metals isn't always permanent. If the environment changes, like a rise in pH or drop in oxygen, jarosite can dissolve or transform, potentially releasing contaminants back into the environment.

That makes it both a threat and an opportunity. And that's where my research comes in.

Jarosite: A golden sponge to mop up metals
Jarosite-rich material from alongside the creek downstream of the Ottery Mine. Credit: Professor Ed Burton.

Jarosite used to treat acid mine drainage

What started as a scientific curiosity has turned into a passion for understanding how this mineral can help us clean up , decode complex geochemical histories and even peek into the past of another planet.

I've been investigating ways to stabilize or transform jarosite to hold on to contaminants more securely.

One promising approach involves a reduced form of iron we call Fe(II).

Under the right conditions, Fe(II) causes a transformation from jarosite into more stable minerals, like goethite or hematite. These new minerals are less likely to release the toxic metals, offering an environmentally effective solution for managing contaminated soils and mine waste.

We've been designing to mimic these transformations and working with partners in Europe to develop column systems that could be used in the field.

It's exciting to see how a small shift in redox chemistry could one day make a big difference in environmental remediation.

Famous on Mars

When detected jarosite on the surface of Mars, global interest in this humble mineral peaked.

Its presence tells us a lot about the red planet's past. It tells us Mars once had acidic, iron-rich water, just like the environments we study on Earth.

Jarosite teaches us about the interplay between geochemistry, mineralogy and planetary evolution.

Whether on a tailings dam in Australia or a Martian crater, this unassuming yellow mineral tells a rich story about , chemical resilience and environmental transformation.

So yes, while it may not win any beauty contests, jarosite has earned its place as one of my favorite minerals. It reflects the kind of science I love. Deep, interdisciplinary and full of surprises.

Provided by CSIRO

Citation: Jarosite: A golden sponge to mop up metals (2025, June 10) retrieved 12 June 2025 from /news/2025-06-jarosite-golden-sponge-mop-metals.html
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