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Switchable catalytic nanointerfaces can extend hydrogen production system lifespan

A switchable catalyst for cleaner hydrogen: greater efficiency and longer lifespan
Synthesis and characterization of PdSx/CNF. a) Preparation scheme of PdSx/CNF b) STEM- EDS mapping images of PdSx nanoparticles located outside CNF in PdSx/CNF in which C (red), Pd (blue), and S (yellow) atoms are presented. c) HRTEM image of the final PdSx/CNF material. d) HRTEM image of amorphous PdSx particles located at the step-edges (dash circle). e) FFT of a representative PdSx nanoparticle. f) HRTEM image of a PdSx particle outside CNF. g) Size distribution histogram and Gaussian fitting of PdSx nanoparticles. Credit: Advanced Science (2025). DOI: 10.1002/advs.202505104

A research team at CiQUS (University of Santiago de Compostela) has developed a new catalytic material that can be switched on and off at will鈥攁 breakthrough that could significantly extend the lifetime of hydrogen production systems and make the process more efficient and sustainable.

Producing green through water electrolysis鈥攗sing electricity to split water into hydrogen and oxygen鈥攊s one of the most promising routes to clean energy. However, the materials that drive this reaction (called electrocatalysts) often degrade quickly with use. As their activity decreases over time, systems become less efficient and more expensive to operate.

To address this challenge, researchers at the Center for Research in Biological Chemistry and Molecular Materials (CiQUS) have designed a novel hybrid catalyst that can toggle between an active and a resting state through simple electrical adjustments, much like a switch. Their work has been in the journal Advanced Science.

The new material consists of tiny palladium nanoparticles embedded inside hollow carbon nanofibers. These tubular structures are not only protective鈥攑reventing the particles from clumping together and degrading鈥攂ut also play an active role in the switching mechanism.

The key innovation lies in the controlled and reversible activation of the catalyst. By introducing sulfur into the system, the researchers created a dynamic chemical environment where the catalyst can transition between two states. In its active mode, it efficiently promotes hydrogen production. When inactive, it is effectively "paused"鈥攕hielded from processes that would otherwise reduce its effectiveness over time.

"We've developed a catalyst that can be turned on or off as needed," explains CiQUS researcher Mar铆a Gim茅nez L贸pez, who led the study. "This opens the door to smarter, more durable systems for industrial hydrogen production."

The switching process is fully reversible. The catalyst can be reactivated by applying a specific electrical signal, restoring its hydrogen-generating ability. This enables on-demand control, increasing the material's useful life and making better use of valuable resources like palladium.

Beyond this specific system, the researchers believe that the strategy could be applied to other types of catalysts and reactions. "Our findings show that it's possible to improve longevity without compromising performance," adds Gim茅nez L贸pez. "This could make a real impact in clean energy technologies."

More information: Carlos Herreros鈥怢ucas et al, Adaptive Catalytic Nanointerfaces for Controlled Hydrogen Evolution: an in Situ Electrochemical Approach, Advanced Science (2025).

Journal information: Advanced Science

Provided by Center for Research in Biological Chemistry and Molecular Materials

Citation: Switchable catalytic nanointerfaces can extend hydrogen production system lifespan (2025, June 2) retrieved 6 June 2025 from /news/2025-06-switchable-catalytic-nanointerfaces-hydrogen-production.html
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