Dynamic friction at an atomic level. (A) Illustration of the CO molecule being manipulated on a copper surface by a metal tip. (B) Changes in the CO molecule's adsorption states while the tip moves horizontally across the surface. The interaction energies between the tip and CO are represented by different lines: CO on the top site (black curve), on the bridge site (red curve), and on the neighboring top site (blue curve). As the tip progresses, the actual adsorption state of CO follows the solid lines. The transitions between different adsorption sites (green cross) provide key insights into the intricacies of dynamic friction. Credit: Kanazawa University

Friction, an everyday phenomenon, has perplexed scientists for centuries. Though extensively researched, our understanding remains fragmented, primarily due to the multifaceted interactions that span across varying scales. Achieving an accurate grasp of the precise contact conditions between objects has been a longstanding challenge, a feat recently made possible through advancements in scanning probe microscopy.

Yet, even with these technological breakthroughs, the intricacies of dynamic friction—the force needed to maintain the movement of a molecule—have remained elusive. While scientists can measure by moving a on a surface, both the measurement and theoretical understanding of dynamic friction have yet to be fully unveiled.

Now, writing in and , a collaborative team from Kanazawa University (Japan), the Donostia International Âé¶¹ÒùÔºics Center (Spain), and the University of Regensburg (Germany) report their groundbreaking study that dives deep into this challenge. They meticulously examined the manipulation of a carbon monoxide (CO) molecule on a single-crystal copper surface using an .

Backed by ab initio calculations, their findings shed light on how the CO molecule positions change relative to the microscope tip and surface, as well as the relationship between the motion of the molecule induced by the tip, energy dissipation, and both static and dynamic friction.

This research stands out for its unequivocal clarity on the process. Not only does it provide fresh insights into a long-studied phenomenon, but it also paves the way for future studies on energy dissipation relaxation processes.

More information: Norio Okabayashi et al, Dynamic Friction Unraveled by Observing an Unexpected Intermediate State in Controlled Molecular Manipulation, Âé¶¹ÒùÔºical Review Letters (2023).

Norio Okabayashi et al, Energy dissipation of a carbon monoxide molecule manipulated using a metallic tip on copper surfaces, Âé¶¹ÒùÔºical Review B (2023).

Journal information: Âé¶¹ÒùÔºical Review Letters , Âé¶¹ÒùÔºical Review B

Provided by Kanazawa University