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Investigating the flow of fluids with non-monotonic, 'S-shaped' rheology

Investigating the flow of fluids with non-monotonic, 鈥楽-shaped鈥 rheology
Sketch of shear banding (top left) and vorticity banding (top right) as proposed by [18]. For shear banding, the rheological curve 饾湉 (饾浘藱) is single-valued but non-monotonic (bottom left). For vortex banding it is the 饾浘藱(饾湉) curve which is single valued and non-monotonic (bottom right). Credit: The European 麻豆淫院ical Journal E (2024). DOI: 10.1140/epje/s10189-024-00444-5

Water and oil, and some other simple fluids, respond in the same way to all levels of shear stress. These are termed Newtonian fluids, and their viscosity is constant for all stresses although it will vary with temperature. Under different stresses and pressure gradients, other non-Newtonian fluids exhibit patterns of behavior that are much more complex.

Researchers Laurent Talon and Dominique Salin from Universit茅 Paris-Sacly, Paris, France have now shown that under certain circumstances, cornstarch suspensions can display a banding pattern with alternating regions of high and low viscosity. This work has been in The European 麻豆淫院ical Journal E.

Non-Newtonian fluids may exhibit shear thinning, where the viscosity decreases with stress; common examples include ketchups and sauces that can appear almost solid-like at rest. The reverse is shear thickening, in which viscosity increases with stress. Some suspensions exhibit a property called discontinuous shear thickening (DST).

"At low shear stress [these fluids] behave like Newtonian fluids, but at a certain stress value the viscosity increases very steeply," explains Talon.

In 2014, Matthew Wyart of New York University, NY, U.S., and Michael Cates of the University of Edinburgh, Scotland, proposed a similar but even more counter-intuitive and interesting model: a so-called "S-shaped" rheology where the viscosity of a first increases with increasing and then decreases.

Talon and Salin set out to investigate the plausibility of this simulated rheology using a suspension of cornstarch in a straight, cylindrical capillary tube. They observed the expected non-monotonic relationship between pressure and flow rate, but not exactly as predicted: the initially increased with pressure but then suddenly decreased.

"Assuming that the Wyart-Cates model is essentially correct, one solution that would match what we observed could be a 'rheological segregation' or 'streamwise banding' in the tube, in which some regions have a high and others a lower one," explains Talon. "We are continuing to investigate the validity of this proposal, both experimentally and using ."

More information: L. Talon et al, On pressure-driven Poiseuille flow with non-monotonic rheology, The European 麻豆淫院ical Journal E (2024).

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