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November 22, 2024

Novel fluorescent materials developed for real-time visualization of multi-component solvents and temperature

The synthesis route of the donor–acceptor fluorescent dye AFL and the design idea and response mechanism of the AFL-based fluorescencesensor. Credit: Liu Anqi
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The synthesis route of the donor–acceptor fluorescent dye AFL and the design idea and response mechanism of the AFL-based fluorescencesensor. Credit: Liu Anqi

Recently, a research team led by Professor Jiang Changlong at Hefei Institutes of 鶹Ժical Science (HFIPS) of the Chinese Academy of Sciences, developed a new donor-acceptor (D-A) type fluorescent dye called AFL. This dye changes its fluorescence color and intensity depending on solvent polarity and temperature, making it useful for quick visual monitoring.

were published in Advanced Functional Materials.

D-A are important for sensors because they can detect specific molecules or environmental changes. However, many current D-A dyes face issues like fluorescence quenching under certain conditions.

This new AFL, developed by the HFIPS researchers, shows different fluorescence responses depending on solvent polarity. In highly polar solvents, AFL's fluorescence emission shifts, allowing for the detection of solvent polarity.

The team also created a , AFL@TA, by combining AFL with tetradecanoic acid (TA). This composite changes fluorescence intensity based on temperature and viscosity. As temperature increases, the viscosity decreases, leading to lower fluorescence intensity.

AFL@TA composite films, which are flexible and stable, were also developed as a potential temperature sensor. These films showed a clear linear relationship between temperature and fluorescence intensity, making them useful for visual detection in various conditions.

This research opens up new possibilities for D-A fluorescent sensing materials and expands their applications in visual sensing technology.

More information: Anqi Liu et al, Donor–Acceptor Type Solvatochromic Flavonoid Materials Fluorphores for Polarity Sensing and Real‐Time Temperature Monitoring, Advanced Functional Materials (2024).

Journal information: Advanced Functional Materials

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