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By the numbers: Diarylethene crystal orientation controlled for first time

By the numbers: Diarylethene crystal orientation controlled for 1st time
The orientation of powdered crystals of diarylethene can be controlled to form in the shape of straight lines or numerals. Credit: Osaka Metropolitan University

Photomechanical materials made of photochromic crystals, which change their molecular structure reversibly in response to light, have the potential to impact fields from semiconductors to pharmaceuticals. For the first time in the world, an Osaka Metropolitan University team has developed a crystal patterning method demonstrating that it is possible to control the orientation of photochromic crystals known as diarylethenes.

These findings were in Small Methods.

Diarylethene crystals not only change color when exposed to UV light, but also undergo various shape changes as the changes. Graduate School of Engineering student Mami Isobe, lecturer Daichi Kitagawa, and Professor Seiya Kobatake focused on patterning to control the position and orientation of the crystals on a substrate using the sublimation method.

The team fabricated convex structures with a height of several microns and a width of a dozen or so microns on a substrate in the shape of a straight line and numerals from 0 to 20. By sublimating powdered crystals of diarylethene onto the substrate, the researchers demonstrated the ability to control the orientation of the crystals, as well as create minute crystals of diarylethene on convex structures.

"We expect the crystal patterning method developed to be applicable to semiconductor materials and pharmaceuticals, which are low-molecular-weight similar to diarylethene," stated graduate student Isobe.

Professor Kobatake added, "To increase the versatility of this crystal patterning method in the future, we would like to analyze the effect of the size and shape of the convex structures on the on , and quantitatively explain the formation principle of the crystal patterns."

More information: Mami Isobe et al, Patterning of Photochromic Diarylethene Crystals by Sublimation for Morphological Controls, Small Methods (2025).

Journal information: Small Methods

Citation: By the numbers: Diarylethene crystal orientation controlled for first time (2025, January 23) retrieved 19 May 2025 from /news/2025-01-diarylethene-crystal.html
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