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January 24, 2025

Supranano engineering enhances strength and ductility of structural materials

Characterization of the boride nanoparticles in the SS-alloy. Credit: Science (2025). DOI: 10.1126/science.adr4917
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Characterization of the boride nanoparticles in the SS-alloy. Credit: Science (2025). DOI: 10.1126/science.adr4917

Building on their work on the first-ever supranano magnesium alloy, a research team led by City University of Hong Kong (CityUHK) has demonstrated how supranano engineering can lead to higher strength and higher ductility in bulk structural materials.

The findings have been in Science under the title, "Ductilization of 2.6-GPa alloys via short-range ordered interfaces and supranano precipitates."

The ultimate problem that the CityUHK-led team has set out to solve is related to the strength and ductility of materials made from metals, for example, steel or titanium, said Professor Lu Jian, Dean of CityUHK's College of Engineering.

"If we want to create stronger and more ductile materials, we need to guard against producing alloys that inevitably show decreased strain-hardening capacity over time," Professor Lu said.

The unique approach adopted by Professor Lu's team is successfully controlling the arrangement and design of the grain interiors and boundaries of a fine-grained alloy at the supranano level, i.e., below 10 nanometers.

"We have previously worked on magnesium alloys but for this project, we used a multicomponent blend of metals for synthesis," Professor Lu explained, adding the three collaborative research groups under his team include his former Ph.D. students and postdocs conducting research on supra-nano-dual-phase structures. They are now professors and research leaders at Xi'an Jiaotong University.

They discovered that the supranano ordering helped to promote a continuously increased flow stress until the fracture of the alloy at a remarkable 10% strain with an equally impressive 2.6-gigapascal (GPa) tensile stress.

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"The yield strength of nanostructured fine-grained alloys is usually less than 1.5 to 2 GPa," he said.

Essentially, Professor Lu continues, the CityUHK-led team found that supranano orderings have a stronger pinning effect for dislocations and stacking faults (SFs). It makes the motion of dislocations and SFs slow, which increases the possibility of their interaction and entanglement with other moveable dislocations, and which promotes multiplication and accumulation of these defects upon loading.

"The supranano orderings with precipitates are uniformly distributed in the grain interior, and thus, the distribution of the generated defects is also uniform, which alleviates strain localization, leading to mutually complementary strengthening and ductilisation and facilitating a high strain-hardening rate and large elongation," Professor Lu said.

Fine-tuning these supranano engineering techniques will further enhance the strength and ductility of different materials, leading to a spectrum of applications in aerospace, automobile, 3C (computer, communication and ) industries, and in construction using super-strong alloys.

More information: Yong-Qiang Yan et al, Ductilization of 2.6-GPa alloys via short-range ordered interfaces and supranano precipitates, Science (2025).

Journal information: Science

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Supranano engineering significantly enhances the strength and ductility of structural materials by controlling grain interiors and boundaries at the supranano level, below 10 nm. This approach promotes increased flow stress and tensile strength, achieving a 2.6 GPa tensile stress at 10% strain. The supranano orderings effectively pin dislocations and stacking faults, leading to uniform defect distribution and improved strain-hardening rates, offering potential applications in various industries.

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