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Atomic-scale copper arrangements steer reactions to produce hydrogen or methane

Atomic arrangements unlock hidden pathways to sustainable energy
Credit: Advanced Functional Materials (2025). DOI: 10.1002/adfm.202514183

Scientists have discovered a way to control chemical reactions by carefully arranging copper atoms on a carbon-based material. With just tiny changes at the atomic scale, the same material can be switched to produce either hydrogen or methane from simple starting ingredients.

published in Advanced Functional Materials, a collaborative team from the National Synchrotron Radiation Research Center in Taiwan (experimental group) and the Center for Condensed Matter Sciences, National Taiwan University (theoretical/computational group), demonstrated how engineering of copper on graphitic carbon nitride (g-C鈧僋鈧) can control .

The researchers found that placed individually or in clusters on g-C鈧僋鈧 predominantly catalyze hydrogen evolution. In contrast, pairs of copper atoms embedded within g-C鈧僋鈧 selectively convert carbon dioxide into methane, achieving an efficiency of 88%. This high selectivity not only makes methane production practical but also highlights a promising route for clean energy applications.

The findings reveal that even subtle differences in atomic arrangement can dramatically alter catalytic behavior. By precisely tuning the positions of copper atoms, it becomes possible to direct the reaction toward desired products, illustrating the power of atom-level control in material design.

"This study shows the potential of atomic design," says Michitoshi Hayashi, the study's corresponding author. "By simply changing where the copper atoms are positioned, we can guide the reaction along the pathway we want, enabling over chemical transformations."

The work emphasizes the broader implications of atom-by-atom engineering, providing insights that could accelerate the development of next-generation catalysts and materials for sustainable energy. By leveraging such precise structural control, researchers aim to design catalysts that efficiently produce fuels and chemicals, ultimately reducing dependence on fossil resources while advancing clean energy technologies.

More information: Wan鈥怲ing Chen et al, Highly Selective Toward HER or CO2RR by Regulating Cu Single and Dual Atoms on g鈥怌3N4, Advanced Functional Materials (2025).

Journal information: Advanced Functional Materials

Citation: Atomic-scale copper arrangements steer reactions to produce hydrogen or methane (2025, August 20) retrieved 21 August 2025 from /news/2025-08-atomic-scale-copper-reactions-hydrogen.html
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