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Fullerene emerges as an efficient, metal-free catalyst for clean energy

Fullerene's role as an efficient, metal-free catalyst for clean energy
Overview of CO2RR activity analysis for 2,562 reported catalysts spanning the past decade. Credit: Angewandte Chemie International Edition (2025). DOI: 10.1002/anie.202511924

Fullerene is a cage-shaped molecule that has a lot of potential to boost the efficiency of catalytic systems. It works well as an electron buffer, which improves the efficiency of reactions such as hydrogen evolution, oxygen reduction, and carbon dioxide (CO2) reduction.

Integrating fullerene into catalytic systems can greatly improve performance in numerous areas, which positions it as a promising material to promote green technologies. Not only does it improve performance, but it is potentially more affordable than other available options as well.

A research team at Tohoku University has used a special model to classify how C60 behaves in order to predict its utility during electrochemical reactions.

They found that its unique structure stabilizes COOH* intermediates across different pH conditions. They compared their models with to reveal new insights on C60-based catalysts and the mechanisms behind their beneficial activity. The results are in Angewandte Chemie International Edition.

"The findings open new possibilities for designing efficient, metal-free catalysts鈥攚hich are more sustainable," says Hao Li (WPI-AIMR, Tohoku University), "This work aligns perfectly with global efforts to reduce CO2 emissions and combat climate change."

Fullerene's role as an efficient, metal-free catalyst for clean energy
pH-dependent microkinetic CO2RR volcano models at the RHE scale and rate-determining analysis of C60-based catalysts. Credit: Angewandte Chemie International Edition (2025). DOI: 10.1002/anie.202511924

Building on their discovery, the research team's next steps will focus on systematically exploring how surface curvature influences catalytic behavior across various electrochemical reactions. They aim to extend the application of C60 and other curved carbon nanostructures to reactions such as nitrate or nitrogen reduction, and to design hybrid catalysts with tunable curvature. The more their model advances, the better we can take advantage of this useful molecule for producing clean energy.

All the experimental and are also available in the Digital Catalysis Platform (), the first catalysis developed by the Hao Li Lab.

More information: Si鈥怶ei Ying et al, C60 Fullerene as the Active Site for CO2 Electroreduction, Angewandte Chemie International Edition (2025).

Provided by Tohoku University

Citation: Fullerene emerges as an efficient, metal-free catalyst for clean energy (2025, August 20) retrieved 20 August 2025 from /news/2025-08-fullerene-emerges-efficient-metal-free.html
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