Crystal structures and CO2 sorption isotherms for compounds 1–5. Credit: Nature Chemistry (2025). DOI: 10.1038/s41557-025-01943-4

A team of researchers has developed a new type of material that could make the process of separating gases cleaner and more energy-efficient.

The breakthrough, in the journal Nature Chemistry, could play a key role in reducing from industrial gas use, such as in , and hydrogen generation—important steps in the move away from fossil fuels.

Gas separation is widely used to remove (CO2) from mixed gases, but current methods are often costly and energy-intensive. The new materials, developed by researchers at the Universities of Strathclyde and Sheffield, are crystals that behave in a unique way. They capture CO2 using a mechanism inspired by how it dissolves in some liquids, rather than filtering it through tiny holes like many current technologies.

The crystals are lined with fluorine-based chains, which respond to pressure by creating temporary openings that trap CO2 gas. Methane, the main component of natural gas, is pushed out in the process, resulting in a cleaner product.

Importantly, the team can fine-tune the material to work under different conditions by adjusting the length of the molecular chains inside the crystals. This flexibility could make the materials suitable for a wide range of industrial uses.

Professor Ashleigh Fletcher from the University of Strathclyde's Department of Chemical & Process Engineering, said, "Our discovery that non-porous silver coordination polymers can selectively capture COâ‚‚ through a dissolution-like mechanism opens up exciting possibilities for next-generation gas separation technologies."

By offering over gas separation with less energy input, it is hoped that the discovery could lead to more sustainable and cost-effective methods in sectors including energy, manufacturing and environmental management.

More information: Iñigo J. Vitórica-Yrezábal et al, Selective CO2 uptake mimics dissolution in highly fluorinated non-porous crystalline materials, Nature Chemistry (2025).

Journal information: Nature Chemistry